Allyl ester protecting group

Allyl Ester Protecting Group. A process is disclosed for the deprotection of allylic esters and ethers. Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 both PDF and HTML across all institutions and individuals. 1 The most essential feature of this protective group is its stability towards both acidic and basic conditions. Under these conditions aryl allyl ethers can be cleaved selectively in the presence of alkyl allyl ethers.

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The allyl group is a commonly used protecting group for alcohols with relative stability towards both acidic and basic conditions that permits orthogonal protection strategies. At this point it was dear mat an excellent method for removing allyl ester protecting groups had been achieved. These conditions are also effective in the deprotection of allyloxycarbonyl groups. A safe facile and lowleaching up to 004ppm method has been developed for the removal of allyl prenyl and benzyl protecting groups from the corresponding esters using a sulfurmodified goldsupported palladium SAPd nanoparticle catalyst. Isomerization to the more labile enol ether employing KOtBu with subsequent mild acidic hydrolysis is one of the most common deprotection methods. Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 both PDF and HTML across all institutions and individuals.

Thus allyl esters are especially useful when carboxylate groups must be protected under in both acidic and basic environments or when.

1026 Fmoc-ArgPmc-OH vs Fmoc-ArgPbf-OH in Peptide Synthesis. Like the Aloc group allyl esters are stable under a wide variety of conditions and can be removed using the same procedure as for Aloc groups. For simplicity and economy allyl alcohol or an. Nach der Durchführung der gewünschten Reaktion an anderer Stelle des Moleküls wird die Schutzgruppe. Allyl esters as carboxy protecting groups in the synthesis of O-glycopeptides. Typical allylic alcohols are those such as allyl alcohol crotyl alcohol and cinnamyl alcohol or the activated esters thereof.

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